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Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Merlene Ottey | JAM | 10.93 |
| 2 | Gwen Torrence | USA | 10.97 |
| 3 | Marina Trandenkova | RUS | 11.07 |
| 4 | Zhanna Pintusevych | UKR | 11.14 |
| 5 | Chioma Ajunwa | NGR | 11.14 |
| 6 | D'Andre Hill | USA | 11.20 |
| 7 | Debbie Ferguson | BAH | 11.28 |
| 8 | Odiah Sidibe | FRA | 11.35 |
| Rank | Name | Nation | Time |
| 1 | Gail Devers | USA | 11.00 |
| 2 | Mary Onyali | NGR | 11.04 |
| 3 | Natalya Voronova | RUS | 11.07 |
| 4 | Chandra Sturrup | BAH | 11.07 |
| 5 | Juliet Cuthbert | JAM | 11.07 |
| 6 | Melanie Paschke | GER | 11.14 |
| 7 | Irina Privalova | RUS | 11.31 |
| 8 | Lucrecia Jardim | POR | 11.32 |