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Date: 3 August 1992 / 5 August 1992 / 6 August 1992
Heats
Quarter-finals
Semi-finals
Final
| Rank | Name | Nation | Time |
| 1 | Gwen Torrence | USA | 21.81 |
| 2 | Juliet Cuthbert | JAM | 22.02 |
| 3 | Merlene Ottey | JAM | 22.09 |
| 4 | Irina Privalova | EUN | 22.19 |
| 5 | Carlette Guidry | USA | 22.30 |
| 6 | Grace Jackson Small | JAM | 22.58 |
| 7 | Michelle Finn | USA | 22.61 |
| 8 | Galina Malchugina | EUN | 22.63 |
| Semi-finals | |||
| 9 | Mary Onyali | NGR | 22.60 |
| 9 | Silke Knoll | GER | 22.60 |
| 11 | Pauline Davis | BAH | 22.61 |
| 12 | Jenny Stoute | GBR | 23.01 |
| 13 | Melinda Gainsford | AUS | 23.03 |
| 14 | Elinda Vorster | RSA | 23.08 |
| 15 | Sisko Hanhijoki | FIN | 23.26 |
| 16 | Aneliya Nuneva | BUL | |
| Quarter-finals | |||
| 17 | Marina Trandenkova | EUN | 22.50 |
| 18 | Wang Huei-Chen | TPE | 22.93 |
| 19 | Lucrecia Jardim | POR | 23.09 |
| 20 | Sabine Gunther | GER | 23.10 |
| 21 | Andrea Thomas | GER | 23.19 |
| 22 | Karin De Lange | NED | 23.41 |
| 22 | Sabine Troger | AUT | 23.41 |
| 24 | Simmone Jacobs | GBR | 23.61 |
| 25 | Lalao Ravaoniriana | MAD | 23.63 |
| 26 | Valerie Jean-Charles | FRA | 23.64 |
| 27 | Iolanda Oanta | ROU | 23.75 |
| 28 | Karen Clarke | CAN | 23.80 |
| 29 | Damayanthi Dharsha | SRI | 23.89 |
| 30 | Georgette Nkoma | CMR | 24.06 |
| 31 | Heather Samuel | ANT | 24.12 |
| 32 | Ruth Morris | ISV | 24.26 |
| Heats | |||
| 33 | Melissa Moore | AUS | 23.86 |
| 34 | Maguy Nestoret | FRA | 24.15 |
| 34 | Gaily Dube | ZIM | 24.15 |
| 36 | Olga Mutanda | CIV | 24.19 |
| 37 | My Linh Truong Hoang | VIE | 24.45 |
| 38 | Agnes Kozary | HUN | 24.50 |
| 39 | Prisca Phillip | BAR | 24.56 |
| 40 | Ngozi Mwanamwambwa | ZAM | 24.59 |
| 41 | Zoila Stewart | CRC | 24.64 |
| 42 | Melrose Mansaray | SLE | 24.67 |
| 43 | Nednapa Chommuak | THA | 24.76 |
| 44 | Dawnnette Douglas | BER | 25.03 |
| 45 | Vaciseva Tavaga | FIJ | 25.07 |
| 46 | Deirdre Caruana | MLT | 25.28 |
| 47 | Manda Kanoute | MLI | 26.03 |
| 48 | Ruth Mangue | GEQ | 27.65 |
| Did not finish | |||
| Oumou Sow | GUI | ||
| Disqualified | |||
| Chen Zhaojing | CHN | ||
| Jaqueline Soliz Inturias | BOL | ||
| Did not start | |||
| Marcel Winkler | RSA | ||
| N'deye Binta Dia | SEN | ||