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Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Marie-Jose Perec | FRA | 22.07 |
| 2 | Mary Onyali | NGR | 22.16 |
| 3 | Juliet Cuthbert | JAM | 22.24 |
| 4 | Inger Miller | USA | 22.33 |
| 5 | Dannette Young | USA | 22.49 |
| 6 | Cathy Freeman | AUS | 22.78 |
| 7 | Natalya Safronnikova | BLR | 22.98 |
| Did not start | |||
| Irina Privalova | RUS | ||
| Rank | Name | Nation | Time |
| 1 | Merlene Ottey | JAM | 22.08 |
| 2 | Galina Malchugina | RUS | 22.35 |
| 3 | Chandra Sturrup | BAH | 22.54 |
| 4 | Carlette Guidry | USA | 22.56 |
| 5 | Melinda Gainsford-Taylor | AUS | 22.76 |
| 6 | Melanie Paschke | GER | 22.81 |
| 7 | Alenka Bikar | SLO | 22.82 |
| 8 | Ekaterini Koffa | GRE | 23.20 |