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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Carlette Guidry | USA | 22.37 |
| 2 | Mary Onyali | NGR | 22.42 |
| 3 | Melanie Paschke | GER | 22.93 |
| 4 | Patricia Rodriguez | COL | 23.13 |
| 5 | Yan Jiankui | CHN | 23.21 |
| 6 | Myra Mayberry | PUR | 23.23 |
| 7 | Zlatka Georgieva | BUL | 24.05 |
| 8 | Laure Kuetey | BEN | 25.57 |
| Rank | Name | Nation | Time |
| 1 | Dannette Young | USA | 22.65 |
| 2 | Melinda Gainsford-Taylor | AUS | 22.70 |
| 3 | Lucrecia Jardim | POR | 22.95 |
| 4 | Viktoriya Fomenko | UKR | 23.18 |
| 5 | Sandra Myers | ESP | 23.18 |
| 6 | Calister Ubah | NGR | 23.34 |
| 7 | Dora Kyriakou | CYP | 23.85 |
| 8 | M'Mah Toure | GUI | 26.64 |
| Rank | Name | Nation | Time |
| 1 | Juliet Cuthbert | JAM | 23.03 |
| 2 | Irina Privalova | RUS | 23.16 |
| 3 | Cathy Freeman | AUS | 23.25 |
| 4 | Sanna Hernesniemi | FIN | 23.35 |
| 5 | Mireille Donders | SUI | 23.52 |
| 6 | Maia Azarashvili | GEO | 23.63 |
| 7 | Felipa Palacios | COL | 24.12 |
| 8 | Lineo Shoai | LES | 26.25 |
| Rank | Name | Nation | Time |
| 1 | Merlene Ottey | JAM | 22.92 |
| 2 | Katharine Merry | GBR | 23.14 |
| 3 | Monika Gachevska | BUL | 23.30 |
| 4 | Heather Samuel | ANT | 23.34 |
| 5 | Ameerah Bello | ISV | 23.45 |
| 6 | Du Xiujie | CHN | 23.69 |
| 7 | Guilhermina da Cruz | ANG | 24.92 |
| Did not start | |||
| Marina Trandenkova | RUS | ||
| Rank | Name | Nation | Time |
| 1 | Galina Malchugina | RUS | 22.63 |
| 2 | Chandra Sturrup | BAH | 22.63 |
| 3 | Beverly McDonald | JAM | 23.04 |
| 4 | Zhanna Pintusevych | UKR | 23.15 |
| 5 | Simmone Jacobs | GBR | 23.36 |
| 6 | Tara Perry | CAN | 23.46 |
| 7 | Marina Zivkovic | SCG | 23.51 |
| 8 | Kaltouma Nadjina | CHA | 24.47 |
| Rank | Name | Nation | Time |
| 1 | Marie-Jose Perec | FRA | 22.62 |
| 2 | Inger Miller | USA | 22.74 |
| 3 | Alenka Bikar | SLO | 22.88 |
| 4 | Ekaterini Koffa | GRE | 23.09 |
| 5 | Natalya Safronnikova | BLR | 23.14 |
| 6 | Sevatheda Fynes | BAH | 23.39 |
| 7 | Georgette Nkoma | CMR | 23.68 |
| 8 | Lyudmila Dmitriadi | UZB | 24.88 |