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Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Allyson Felix | USA | 22.36 |
| 2 | Abiodun Oyepitan | GBR | 22.56 |
| 3 | Ivet Lalova | BUL | 22.56 |
| 4 | Muna Lee | USA | 22.69 |
| 5 | Maryna Maydanova | UKR | 22.75 |
| 6 | Beverly McDonald | JAM | 23.02 |
| 7 | Christine Arron | FRA | 23.05 |
| Did not finish | |||
| Merlene Ottey | SLO | ||
| Rank | Name | Nation | Time |
| 1 | Veronica Campbell | JAM | 22.13 |
| 2 | Aleen Bailey | JAM | 22.33 |
| 3 | Kim Gevaert | BEL | 22.48 |
| 4 | Debbie Ferguson | BAH | 22.49 |
| 5 | Cydonie Mothersill | CAY | 22.76 |
| 6 | LaShauntea Moore | USA | 22.93 |
| 7 | Sylviane Felix | FRA | 22.99 |
| 8 | Olga Kaidantzi | GRE | 23.30 |