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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Veronica Campbell | JAM | 22.59 |
| 2 | Alenka Bikar | SLO | 23.09 |
| 3 | LaShauntea Moore | USA | 23.10 |
| 4 | Lucimar Moura | BRA | 23.40 |
| 5 | Heide Seyerling | RSA | 23.66 |
| 6 | Monika Gachevska | BUL | 23.71 |
| Rank | Name | Nation | Time |
| 1 | Ivet Lalova | BUL | 22.88 |
| 2 | Sylviane Felix | FRA | 22.94 |
| 3 | Yekaterina Kondratyeva | RUS | 23.03 |
| 4 | Natalya Safronnikova | BLR | 23.28 |
| 5 | Lyubov Perepelova | UZB | 24.10 |
| 6 | Gretta Taslakian | LBN | 24.30 |
| Rank | Name | Nation | Time |
| 1 | Cydonie Mothersill | CAY | 22.40 |
| 2 | Beverly McDonald | JAM | 22.90 |
| 3 | Yelena Bolsun | RUS | 23.00 |
| 4 | Joice Maduaka | GBR | 23.15 |
| 5 | Saraswati Saha | IND | 23.43 |
| 6 | Gcinile Moyane | SWZ | 25.62 |
| Rank | Name | Nation | Time |
| 1 | Allyson Felix | USA | 22.39 |
| 2 | Abiodun Oyepitan | GBR | 22.50 |
| 3 | Maryna Maydanova | UKR | 22.76 |
| 4 | Muriel Hurtis | FRA | 22.77 |
| 5 | Karin Mayr-Krifka | AUT | 22.81 |
| 6 | Mary Onyali-Omagbemi | NGR | 23.37 |
| 7 | Gladys Thompson | LBR | 27.51 |
| Rank | Name | Nation | Time |
| 1 | Muna Lee | USA | 22.57 |
| 2 | Tatyana Levina | RUS | 23.05 |
| 3 | LaVerne Jones | ISV | 23.20 |
| 4 | Marilia Gregoriou | CYP | 23.23 |
| 5 | Emma Wade | BIZ | 23.43 |
| 6 | Michelle Banga Moudzoula | CGO | 24.37 |
| Rank | Name | Nation | Time |
| 1 | Aleen Bailey | JAM | 22.73 |
| 2 | Kim Gevaert | BEL | 22.76 |
| 3 | Olga Kaidantzi | GRE | 23.11 |
| 4 | Fabienne Feraez | BEN | 23.12 |
| 5 | Johanna Manninen | FIN | 23.45 |
| 6 | Kadiatou Camara | MLI | 23.56 |
| Rank | Name | Nation | Time |
| 1 | Debbie Ferguson | BAH | 22.57 |
| 2 | Christine Arron | FRA | 22.60 |
| 3 | Merlene Ottey | SLO | 22.72 |
| 4 | Lauren Hewitt | AUS | 22.87 |
| 5 | Digna Luz Murillo | COL | 22.98 |
| 6 | Anna Pacholak | POL | 23.00 |