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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Marion Jones | USA | 22.75 |
| 2 | Cydonie Mothersill | CAY | 22.78 |
| 3 | Felipa Palacios | COL | 23.08 |
| 4 | Oxana Ekk | RUS | 23.17 |
| 5 | Fatima Yusuf-Olukoju | NGR | 23.21 |
| 6 | Alenka Bikar | SLO | 23.26 |
| 7 | Monica Twum | GHA | 23.51 |
| Rank | Name | Nation | Time |
| 1 | Myriam Mani | CMR | 22.68 |
| 2 | Muriel Hurtis | FRA | 23.04 |
| 3 | Cathy Freeman | AUS | 23.11 |
| 4 | Juliet Campbell | JAM | 23.18 |
| 5 | Sarah Reilly | IRL | 23.43 |
| 6 | Zuzanna Radecka | POL | 23.57 |
| 7 | Kaltouma Nadjina | CHA | 23.81 |
| 8 | Hana Ali Saleh | YEM | 30.36 |
| Rank | Name | Nation | Time |
| 1 | Lauren Hewitt | AUS | 23.07 |
| 2 | Mercy Nku | NGR | 23.14 |
| 3 | Nanceen Perry | USA | 23.18 |
| 4 | Johanna Manninen | FIN | 23.40 |
| 5 | Ekaterini Koffa | GRE | 23.53 |
| 6 | Lineo Shoai | LES | 25.57 |
| Did not start | |||
| Manuela Levorato | ITA | ||
| Andrea Philipp | GER | ||
| Rank | Name | Nation | Time |
| 1 | Melinda Gainsford-Taylor | AUS | 22.71 |
| 2 | Louise Ayetotche | CIV | 22.85 |
| 3 | Chandra Sturrup | BAH | 23.09 |
| 4 | Olena Pastushenko | UKR | 23.64 |
| 5 | Lyubov Perepelova | UZB | 23.83 |
| 6 | Karin Mayr | AUT | 23.90 |
| 7 | Akonga Nsimbo | COD | 25.35 |
| Did not start | |||
| Ameerah Bello | ISV | ||
| Rank | Name | Nation | Time |
| 1 | Beverly McDonald | JAM | 22.50 |
| 2 | Pauline Davis-Thompson | BAH | 22.61 |
| 3 | Irina Khabarova | RUS | 23.21 |
| 4 | Valma Bass | SKN | 23.37 |
| 5 | Mireille Donders | SUI | 23.44 |
| 6 | Liu Xiaomei | CHN | 23.56 |
| 7 | Joanne Durant | BAR | 23.90 |
| 8 | Heather Samuel | ANT | 24.44 |
| Rank | Name | Nation | Time |
| 1 | Mary Onyali-Omagbemi | NGR | 22.90 |
| 2 | Debbie Ferguson | BAH | 23.19 |
| 3 | Sabrina Mulrain | GER | 23.31 |
| 4 | Astia Walker | JAM | 23.33 |
| 5 | Samantha Davies | GBR | 23.36 |
| 6 | Qin Wangping | CHN | 24.10 |
| 7 | Mila Savic | SCG | 24.12 |
| 8 | Monika Gachevska | BUL | 24.16 |
| Rank | Name | Nation | Time |
| 1 | Susanthika Jayasinghe | SRI | 22.53 |
| 2 | Zhanna Pintusevych | UKR | 23.13 |
| 3 | Torri Edwards | USA | 23.29 |
| 4 | Marina Trandenkova | RUS | 23.31 |
| 5 | Joice Maduaka | GBR | 23.36 |
| 6 | Aida Diop | SEN | 23.46 |
| 7 | Hellena Wrappah | GHA | 23.64 |