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Date: 15 August 2008
Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Cesar Cielo Filho | BRA | 21.34 |
| 2 | Stefan Nystrand | SWE | 21.71 |
| 3 | Eamon Sullivan | AUS | 21.75 |
| 4 | Krisztian Takacs | HUN | 21.84 |
| 5 | Duje Draganja | CRO | 21.85 |
| 6 | George Bovell III | TTO | 21.86 |
| 7 | Gideon Louw | RSA | 21.97 |
| 8 | Rafed Ziad El-Masri | GER | 22.09 |
| Rank | Name | Nation | Time |
| 1 | Alain Bernard | FRA | 21.54 |
| 2 | Ashley Callus | AUS | 21.68 |
| 3 | Roland Schoeman | RSA | 21.74 |
| 4 | Amaury Leveaux | FRA | 21.76 |
| 4 | Ben Wildman-Tobriner | USA | 21.76 |
| 6 | Garrett Weber-Gale | USA | 22.08 |
| 7 | Bartosz Kizierowski | POL | 22.12 |
| 8 | Nicholas Santos | BRA | 22.15 |