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Dates: 9 August 2008-16 August 2008
Heats
Repechages
Final
| Rank | Name | Nation | Time |
| 1 | Georgeta Andrunache; Viorica Susanu | ROU | 7:20.60 |
| 2 | Wu You; Gao Yulan | CHN | 7:22.28 |
| 3 | Yuliya Bichik; Nataliya Gelakh | BLR | 7:22.91 |
| 4 | Lenka Wech; Maren Derlien | GER | 7:25.73 |
| 5 | Juliette Haigh; Nicky Coles | NZL | 7:28.80 |
| 6 | Louisa Reeve; Olivia Whitlam | GBR | 7:33.61 |
| Final B | |||
| 7 | Portia McGee; Anna Cummins | USA | 7:33.17 |
| 8 | Inène Pascal-Pretre; Stéphanie Dechand | FRA | 7:36.25 |
| 9 | Zoë Hoskins; Sabrina Kolker | CAN | 7:37.27 |
| 10 | Kim Crow; Sarah Cook | AUS | 7:40.93 |