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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Shawn Crawford | USA | 20.61 |
| 2 | Marcin Jedrusinski | POL | 20.64 |
| 3 | Stéphane Buckland | MRI | 20.98 |
| 4 | Jiri Vojtik | CZE | 21.05 |
| 5 | Fanuel Kenosi | BOT | 21.09 |
| 6 | Adam Harris | GUY | 21.36 |
| 7 | Khalil Al-Hanahneh | JOR | 21.55 |
| 8 | Solomon Bayoh | SLE | 22.16 |
| Did not start | |||
| Francis Obikwelu | POR | ||
| Rank | Name | Nation | Time |
| 1 | Brian Dzingai | ZIM | 20.25 |
| 2 | Christian Malcolm | GBR | 20.42 |
| 3 | Chris Williams | JAM | 20.53 |
| 4 | Shinji Takahira | JPN | 20.58 |
| 5 | Amr Seoud | EGY | 20.75 |
| 6 | Thuso Mpuang | RSA | 20.87 |
| 7 | Daniel Grueso | COL | 21.15 |
| 8 | Arnaldo Abrantes | POR | 21.46 |
| Rank | Name | Nation | Time |
| 1 | Marlon Devonish | GBR | 20.49 |
| 2 | Kim Collins | SKN | 20.55 |
| 3 | Marvin Anderson | JAM | 20.85 |
| 4 | Matic Osovnikar | SLO | 20.89 |
| 5 | Chris Lloyd | DMA | 20.90 |
| 6 | Heber Viera | URU | 20.93 |
| 7 | Cristian Reyes | CHI | 21.20 |
| 8 | Franklin Nazareno | ECU | 21.26 |
| Rank | Name | Nation | Time |
| 1 | Roman Smirnov | RUS | 20.76 |
| 2 | Walter Dix | USA | 20.77 |
| 3 | Rolando Palacios | HON | 20.81 |
| 4 | Ángel David Rodríguez | ESP | 20.87 |
| 5 | Bruno de Barros | BRA | 21.15 |
| 6 | Desislav Gunev | BUL | 21.55 |
| 7 | Vyacheslav Muravyov | KAZ | 21.68 |
| 8 | Nicolai Portelli | MLT | 22.31 |
| Rank | Name | Nation | Time |
| 1 | Rondell Sorillo | TTO | 20.58 |
| 2 | Usain Bolt | JAM | 20.64 |
| 3 | Kristof Beyens | BEL | 20.69 |
| 4 | Marc Schneeberger | SUI | 20.86 |
| 5 | Jose Acevedo | VEN | 21.06 |
| 6 | Ihor Bodrov | UKR | 21.38 |
| 7 | Mohamad Siraj Tamim | LBN | 21.80 |
| 8 | Oleg Juravlyov | UZB | 22.31 |
| 9 | Juan Zeledon | NCA | 23.39 |
| Rank | Name | Nation | Time |
| 1 | Wallace Spearmon | USA | 20.46 |
| 2 | Jaysuma Saidy Ndure | NOR | 20.54 |
| 3 | Paul Hession | IRL | 20.59 |
| 4 | Seth Amoo | GHA | 20.91 |
| 5 | Ronalds Arajs | LAT | 21.22 |
| 6 | Jayson Jones | BIZ | 21.54 |
| 7 | Nabie Foday Fofanah | GUI | 21.68 |
| Did not finish | |||
| Bryan Barnett | CAN | ||
| Rank | Name | Nation | Time |
| 1 | Obinna Metu | NGR | 20.62 |
| 2 | Ramil Guliyev | AZE | 20.78 |
| 3 | Churandy Martina | AHO | 20.78 |
| 4 | Sandro Viana | BRA | 20.84 |
| 5 | Jamaal Rolle | BAH | 20.93 |
| 6 | Shingo Suetsugu | JPN | 20.93 |
| 7 | Omar Jouma Al-Salfa | UAE | 21.00 |
| Did not start | |||
| Alex Nelson | GBR | ||
| Rank | Name | Nation | Time |
| 1 | Aaron Armstrong | TTO | 20.57 |
| 2 | Brendan Christian | ANT | 20.58 |
| 3 | Jared Connaughton | CAN | 20.60 |
| 4 | Visa Hongisto | FIN | 20.62 |
| 5 | Marco Cribari | SUI | 20.98 |
| 6 | James Dolphin | NZL | 20.98 |
| 7 | Zhang Peimeng | CHN | 21.06 |
| Did not start | |||
| Samuel Francis | QAT | ||