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Date: 19 August 2004
Summary
Semi-final 1
| Rank | Name | Nation | Time |
| 1 | Roland Schoeman | RSA | 21.99 |
| 2 | Brett Hawke | AUS | 22.07 |
| 3 | Salim Iles | ALG | 22.16 |
| 4 | Julien Sicot | FRA | 22.26 |
| 5 | Frederick Bousquet | FRA | 22.29 |
| 6 | Javier Noriega | ESP | 22.36 |
| 7 | Lyndon Ferns | RSA | 22.46 |
| 8 | Ricardo Busquets Healy | PUR | 22.52 |
| Rank | Name | Nation | Time |
| 1 | Jason Lezak | USA | 22.12 |
| 2 | Gary Hall Jr. | USA | 22.18 |
| 2 | Stefan Nystrand | SWE | 22.18 |
| 2 | Oleksandr Volynets | UKR | 22.18 |
| 5 | Duje Draganja | CRO | 22.19 |
| 6 | Bartosz Kizierowski | POL | 22.22 |
| 7 | Fernando Scherer | BRA | 22.27 |
| 8 | Karel Novy | SUI | 22.63 |