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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Yuliya Bichik; Nataliya Gelakh | BLR | 7:27.73 |
| 2 | Katherine Grainger; Cath Bishop | GBR | 7:34.66 |
| 3 | Maren Derlien; Sandra Goldbach | GER | 7:44.00 |
| 4 | Sophie Balmary; Virginie Chauvel | FRA | 7:49.70 |
| 5 | Sarah Jones; Kate Mackenzie | USA | 7:53.78 |
| Rank | Name | Nation | Time |
| 1 | Georgeta Andrunache; Viorica Susanu | ROU | 7:29.74 |
| 2 | Darcy Marquardt; Buffy Williams | CAN | 7:42.36 |
| 3 | Milka Tancheva; Anna Chuk | BUL | 7:52.45 |
| 4 | Cong Huanling; Feng Xueling | CHN | 7:53.30 |
| 5 | Juliette Haigh; Nicky Coles | NZL | 9:37.53 |