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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Vasilios Polymeros; Nikos Skiathitis | GRE | 6:15.22 |
| 2 | Elia Luini; Leonardo Pettinari | ITA | 6:19.82 |
| 3 | Ľuboš Podstupka; Lukáš Babač | SVK | 6:22.00 |
| 4 | Zhu Zhifu; Yang Jian | CHN | 6:22.64 |
| 5 | Armando Arrechavaleta; Yosvel Iglesias | CUB | 6:25.14 |
| 6 | Thiago "Nequinho" Gomes; José Sobral Júnior | BRA | 6:33.92 |
| Rank | Name | Nation | Time |
| 1 | Frédéric Dufour; Pascal Touron | FRA | 6:14.55 |
| 2 | Zsolt Hirling; Tamás Varga | HUN | 6:20.98 |
| 3 | Rubén Álvarez; Juan Zunzunegui | ESP | 6:23.23 |
| 4 | Kazushige Ura; Daisaku Takeda | JPN | 6:24.08 |
| 5 | Ting Wai Lo; Sau Wah So | HKG | 6:43.49 |
| Rank | Name | Nation | Time |
| 1 | Mads Rasmussen; Rasmus Quist | DEN | 6:17.68 |
| 2 | Tomasz Kucharski; Robert Sycz | POL | 6:21.45 |
| 3 | Manuel Brehmer; Ingo Euler | GER | 6:25.22 |
| 4 | George Jelbart; Cameron Wurf | AUS | 6:28.94 |
| 5 | Sergey Bogdanov; Ruslan Naurzaliyev | UZB | 6:52.34 |
| Rank | Name | Nation | Time |
| 1 | Sam Lynch; Gearóid Towey | IRL | 6:16.63 |
| 2 | Steve Tucker; Greg Ruckman | USA | 6:20.00 |
| 3 | Václav Maleček; Michal Vabroušek | CZE | 6:21.82 |
| 4 | Justin Gevaert; Wouter Van der Fraenen | BEL | 6:26.25 |
| 5 | Rodolfo Collazo; Joe Reboledo | URU | 6:29.20 |