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Summary
Heat 1
| Rank | Name | Nation | Time |
| 1 | Stéphane Buckland | MRI | 20.29 |
| 2 | Francis Obikwelu | POR | 20.40 |
| 2 | Juan Pedro Toledo | MEX | 20.40 |
| 4 | Yang Yaozu | CHN | 20.59 |
| 5 | Johan Wissman | SWE | 20.60 |
| 6 | Paul Brizzel | IRL | 21.00 |
| 7 | Nabie Foday Fofanah | GUI | 21.45 |
| Did not start | |||
| Hamed Al-Bishi | KSA | ||
| Rank | Name | Nation | Time |
| 1 | Shawn Crawford | USA | 20.55 |
| 2 | Chris Williams | JAM | 20.57 |
| 3 | Marcin Urbas | POL | 20.71 |
| 4 | Darren Campbell | GBR | 20.72 |
| 5 | Jaysuma Saidy Ndure | GAM | 20.78 |
| 6 | Leigh Julius | RSA | 20.80 |
| 7 | Geronimo Goeloe | AHO | 21.09 |
| 8 | Basilio de Moraes | BRA | 21.14 |
| Rank | Name | Nation | Time |
| 1 | Frankie Fredericks | NAM | 20.54 |
| 2 | Malik Louahla | ALG | 20.67 |
| 3 | David Canal | ESP | 20.72 |
| 4 | Brian Dzingai | ZIM | 20.72 |
| 5 | Heber Viera | URU | 20.94 |
| 6 | Oleg Sergeyev | RUS | 20.95 |
| 7 | Mphelave Dlamini | SWZ | 21.82 |
| Did not finish | |||
| Chris Lambert | GBR | ||
| Rank | Name | Nation | Time |
| 1 | Marcin Jedrusinski | POL | 20.63 |
| 2 | Tobias Unger | GER | 20.65 |
| 3 | Joseph Batangdon | CMR | 20.92 |
| 4 | Geza Pauer | HUN | 21.02 |
| 5 | Usain Bolt | JAM | 21.05 |
| 6 | Christian Nsiah | GHA | 21.06 |
| 7 | Hamoud Abdallah Al Dalhami | OMA | 21.82 |
| 8 | Ryo Matsuda | JPN | 24.59 |
| Rank | Name | Nation | Time |
| 1 | Dominic Demeritte | BAH | 20.62 |
| 2 | Christian Malcolm | GBR | 20.62 |
| 3 | Panayiotis Sarris | GRE | 20.67 |
| 4 | Asafa Powell | JAM | 20.77 |
| 5 | Jiri Vojtik | CZE | 20.79 |
| 6 | Dion Crabbe | IVB | 20.85 |
| 7 | Nazmizan Muhammad | MAS | 21.24 |
| 8 | Adam Miller | AUS | 21.31 |
| Rank | Name | Nation | Time |
| 1 | Bernard Williams | USA | 20.29 |
| 2 | Anastasios Gousis | GRE | 20.44 |
| 3 | Andrew Howe | ITA | 20.55 |
| 4 | Matic Osovnikar | SLO | 20.57 |
| 5 | Till Helmke | GER | 20.73 |
| 6 | Oumar Loum | SEN | 20.97 |
| 7 | Anninos Marcoullides | CYP | 23.94 |
| Rank | Name | Nation | Time |
| 1 | Sebastian Ernst | GER | 20.47 |
| 2 | Justin Gatlin | USA | 20.51 |
| 3 | Marco Torrieri | ITA | 20.68 |
| 4 | Claudio Sousa | BRA | 20.70 |
| 5 | Brendan Christian | ANT | 20.71 |
| 6 | Shinji Takahira | JPN | 21.05 |
| 7 | Dadas Ibrahimov | AZE | 21.60 |
| 8 | Russel Roman | PLW | 24.89 |