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Summary
Quarter-final 1
| Rank | Name | Nation | Time |
| 1 | Francis Obikwelu | POR | 9.93 |
| 2 | Dwight Thomas | JAM | 10.12 |
| 2 | Mark Lewis-Francis | GBR | 10.12 |
| 4 | Ronald Pognon | FRA | 10.15 |
| 5 | Shingo Suetsugu | JPN | 10.19 |
| 6 | Pierre Browne | CAN | 10.21 |
| 7 | Churandy Martina | AHO | 10.24 |
| 8 | Andre da Silva | BRA | 10.34 |
| Rank | Name | Nation | Time |
| 1 | Shawn Crawford | USA | 9.89 |
| 2 | Obadele Thompson | BAR | 10.12 |
| 3 | Vicente de Lima | BRA | 10.26 |
| 4 | Matic Osovnikar | SLO | 10.26 |
| 5 | Deji Aliu | NGR | 10.26 |
| 6 | Nicolas Macrozonaris | CAN | 10.28 |
| 7 | Gennadiy Chernovol | KAZ | 10.42 |
| 8 | Idrissa Sanou | BUR | 10.43 |
| Rank | Name | Nation | Time |
| 1 | Justin Gatlin | USA | 9.96 |
| 2 | Jason Gardener | GBR | 10.15 |
| 3 | Uchenna Emedolu | NGR | 10.15 |
| 4 | Nobuharu Asahara | JPN | 10.24 |
| 5 | Yeoryios Theodoridis | GRE | 10.36 |
| 6 | Roland Nemeth | HUN | 10.38 |
| 7 | Nicconnor Alexander | TTO | 10.48 |
| Did not start | |||
| Eddy De Lepine | FRA | ||
| Rank | Name | Nation | Time |
| 1 | Aziz Zakari | GHA | 10.02 |
| 2 | Kim Collins | SKN | 10.05 |
| 3 | Michael Frater | JAM | 10.11 |
| 4 | Frankie Fredericks | NAM | 10.17 |
| 5 | Joshua Ross | AUS | 10.22 |
| 6 | Alexander Kosenkow | GER | 10.24 |
| 7 | Andrey Yepishin | RUS | 10.29 |
| 8 | Jaysuma Saidy Ndure | GAM | 10.39 |
| Rank | Name | Nation | Time |
| 1 | Maurice Greene | USA | 9.93 |
| 2 | Asafa Powell | JAM | 9.99 |
| 3 | Leo Myles-Mills | GHA | 10.18 |
| 4 | Lukasz Chyla | POL | 10.23 |
| 5 | Kareem Streete-Thompson | CAY | 10.24 |
| 6 | Simone Collio | ITA | 10.29 |
| 7 | Jarbas Mascarenhas | BRA | 10.30 |
| 8 | Eric Pacome N'Dri | CIV | 10.32 |