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Dates: 30 July 2012-3 August 2012
Heats
Repechages
Final
| Rank | Name | Nation | Time |
| 1 | Anna Watkins; Katherine Grainger | GBR | 6:55.82 |
| 2 | Kim Crow; Brooke Pratley | AUS | 6:58.55 |
| 3 | Magdalena Fularczyk; Julia Michalska | POL | 7:07.92 |
| 4 | Wang Min; Zhu Weiwei | CHN | 7:08.92 |
| 5 | Fiona Paterson; Anna Reymer | NZL | 7:09.82 |
| 6 | Margot Shumway; Sarah Trowbridge | USA | 7:10.54 |
| Final B | |||
| 7 | Lenka Antosova; Jitka Antošova | CZE | 7:24.93 |
| 8 | Inge Janssen; Elisabeth Hogerwerf | NED | 7:29.57 |
| 9 | Tina Manker; Stephanie Schiller | GER | 7:33.32 |
| 10 | Anna Kravchenko; Olena Buryak | UKR | 7:36.65 |